Spherical silver nanoparticles may be produced by the reduction of Ag (aq) by borohydride in the presences of citrate. When (phenylphosphinidene) bis-(benzenesulfonic acid) is also present, and the reaction mixture is illuminated, nonspherical Ag nanoparticles are formed. We have discovered that the shape of some Ag nanoparticles can be repeatedly changed by subjecting them to numerous cycles of light and dark. To our knowledge, this has never been reported in the literature. These photo chromic Ag nanoparticles displayed at least two different particle shapes: prismatic and spherical. The difference in morphology could be determined by the color of the solution and by the electronic spectra. The prismatic Ag nanoparticles can be photochemically synthesized in 24hrs and then converted into a spherical form by placing them in the dark for 14hrs. This transformation is accompanied by a blue shift in the visible spectrum. The prismatic particles are reformed by placing them in the light for 4 hrs. This transformation has a red shift in the visible spectrum.
Thesis (M.S.) University of Alaska Fairbanks, 2005
The export option will allow you to export the current search results of the entered query to a file. Different
formats are available for download. To export the items, click on the button corresponding with the preferred download format.
By default, clicking on the export buttons will result in a download of the allowed maximum amount of items.
To select a subset of the search results, click "Selective Export" button and make a selection of the items you want to export.
The amount of items that can be exported at once is similarly restricted as the full export.
After making a selection, click one of the export format buttons. The amount of items that will be exported is indicated in the bubble next to export format.