Browsing University of Alaska Fairbanks by Subject "xanthan gum"
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Laboratory investigation of infiltration process of nonnewtonian fluids through porous media in a non-isothermal flow regime for effective remediation of adsorbed contaminantsContamination of soil and groundwater have serious health implications for man and environment. The overall goal of this research is to study a methodology of using nonNewtonian fluids for effective remediation of adsorbed contaminants in porous media under nonisothermal flow regimes. Non-Newtonian fluids (Guar gum and Xanthan gum solutions) provide a high viscous solution at low concentration and these fluids adjust their viscosities with applied shear rate and change in temperature. Adjustment of viscosity with an applied rate of shear is vital for contaminant remediation because non-Newtonian shear thinning fluids can penetrate to low permeability zones in subsurface by decreasing their viscosities due to high shear rates offered by low permeability zones. The application of non-Newtonian shear thinning fluids for contaminant remediation required the improvement in understanding of rheology and how the factors such as concentration, temperature and change in shear rate impacted the rheology of fluids. In order to study the rheology, we studied the changes in rheological characteristics (viscosity and contact angle) of non-Newtonian fluids of different concentrations (i.e., 0.5g/l, 1g/l, 3g/l, 6g/l and 7g/l) at different temperatures ranging from 0 ºC to 30 ºC. OFITE model 900 viscometer and Tantec contact angle meter were used to record the changes in viscosity of fluids for an applied range of shear rate (i.e., 17.02 s⁻¹ to 1021.38 s⁻¹) and contact angles, respectively, for different concentrations of non-Newtonian fluids. Understanding the flow characteristic of non-Newtonian fluids under low temperature conditions could help in developing methods to effectively remediate contaminants from soils. Results of rheological tests manifested an increase in the viscosity of both polymers with concentration and decrease in temperature. Mid (i.e., 3g/l) to high (i.e., 6g/l and 7g/l) concentrations of polymers manifested higher viscosities compared to 0.5g/l for both polymers. Flow of high viscous solutions required more force to pass through a glass-tube-bundle setup which represented a synthetic porous media to study the flow characteristic and effectiveness of Newtonian and non-Newtonian fluids for contaminant remediation. Low concentrations of 0.5g/l were selected for flow and remediation experiments because this concentration can flow through porous media easily without application of force. The 0.5g/l of Xanthan gum and de-ionized water were used to conduct the infiltration experiments to study the flow characteristics of Newtonian and non-Newtonian fluids at 0.6°C, 5°C and 19°C in synthetic porous media. Infiltration depth of both Newtonian and non-Newtonian fluids would decrease with the decrease in temperature because of the change in their properties like dynamic viscosity, density and angle of contact. The result of comparison of Newtonian and non-Newtonian fluids showed water to be more effective in remediating a surrogate adsorbent contaminant (Dichlobenil) from the synthetic porous media at 19°C. This result was counter-intuitive to what we began with as our hypothesis. However, it was also observed later that 0.5 g/l concentration of Guar gum behaved more like a Newtonian fluid and 0.5 g/l concentration of Xanthan gum had not shown strong non-Newtonian behavior compared to higher concentrations of Xanthan gum. Hence more analysis needs to be done to determine what concentration of non-Newtonian fluid should be more effective for remediation.